Molecular Materials and Functional Polymers by Christian G. Claessens, Werner J. Blau (auth.), Prof. Dr.

By Christian G. Claessens, Werner J. Blau (auth.), Prof. Dr. Werner J. Blau, Prof. Dr. Panagiotis Lianos, Prof. Dr. Ulrich Schubert (eds.)

The articles during this publication summarize the paintings awarded on the ultimate workshop of the price (European Cooperation within the box of clinical and Technical learn) motion on Molecular fabrics and useful Polymers for complex units, which was once held in June 2000 in Patras, Greece. the gathering supplies an exceptional evaluate of the cutting-edge during this box and the development made by way of the coordinated learn tasks. the implications diversity over the synthesis, actual houses, and purposes of molecular fabrics (nanotubes, fullerenes, phthalocyanines), inorganic and inorganic-organic hybrid fabrics, and useful polymers (electronic conduction, photoluminiscence, optical garage, photovoltaic devices).

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DSC analyses disclosed the polyester thermal behaviour. The performed molecular mass investigations substantiated the very attractive film forming properties. Optical storage performance of thin films cast from polyester solutions was investigated through polarization holography. The resulting diffraction efficiency was mapped as a function of irradiation power (see Fig. 2) and exposure time. Frequently a nonlinear response to irradiation power was observed. Polytetradecanedioates with cyano-, nitro-, methyl-, fluoro-, or trifluoromethylazobenzene reached more than 50% diffraction efficiency, and thus provide film materials with excellent first order diffraction properties (resulting from polarization holographic experiments) in the experimental range investigated.

Effect of Ti02 addition on the hydrophobicity of a super-hydrophobic thin film during outdoor exposure; the numbers refer to Ti02 concentration (%(w/w» Super-Hydrophobic Films 37 of Ti02, and 3) reduction of static electricity by the photo-induced hydrophilicity of Ti02 [55]. Surfaces with a high roughness commonly show fewer mechanical properties than flat surfaces, and this is a crucial problem for the application of superhydrophobic surfaces. A needle-like structure is known to constitute an ideal surface for super-hydrophobicity [57].

Most of the azobenzene oligopeptides demonstrated very high surface relief structures which account for the high diffraction efficiencies since no permanent anisotropy can be detected in the films after some days. Dendritics and hyperbranched polyesters Dendritic macromolecules comprising dendrimers and hyperbranched polymers constitute a novel class of highly branched polymers with a multitude of end groups. Whereas dendrimers are described by a well-defined, monodisperse structure, the related family of hyperbranched polymers is characterized by less well-defined, Fig.

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